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High pressure line shapes of the Rb D 1 and D 2 lines for 4 He and 3 He collisions
2016
Journal of Quantitative Spectroscopy and Radiative Transfer
Line shapes for the Rb D 1 (5 2 S 1=2 25 2 P 1=2 ) and D 2 (5 2 S 1=2 25 2 P 3=2 ) transitions with 4 He and 3 He collisions at pressures of 500-15,000 Torr and temperatures of 333-533 K have been experimentally observed and compared to predictions from the Anderson-Talman theory. The ground X 2 Σ þ 1=2 and excited A 2 Π 1=2 , A 2 Π 3=2 , and B 2 Σ þ 1=2 potential energy surfaces required for the line shape predictions have been calculated using a one-electron pseudo-potential technique. The
doi:10.1016/j.jqsrt.2016.06.027
fatcat:nrujmbhhkng7hkskafvkjfmitm