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A series of di-palladium complexes with thiolato ligands containing urea groups for hydrogen bonding have been prepared. Three of these complexes have been structurally characterised by X-ray crystallography showing some interesting supramolecular interactions between the metal complexes and counter-anions. 31 P NMR solution studies have been carried out to gain some insight into the different conformations of the complexes in solution. To support the experimental findings, computationaldoi:10.1080/10610270701297418 fatcat:mslho25cgrdchbnytil3lewuei