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This chapter is dedicated to the studies on phosphate glasses, from their fundamental aspects to their most relevant applications of today. P 2 O 5 -based glasses have experienced a continuously increasing number of published works in the last decades and still they possess a bright potential. Their sometimes intricate structure has made its study a quite relevant field for the Glass Science community which attracts more and more researchers. And, on the other hand, the associated difficultiesdoi:10.1007/978-3-319-93728-1_16 fatcat:ovmfkobtwzcufbn6blfdnedgfu