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The paths of nucleophilic fluoroalkylation reaction of propylene oxide with PhSO 2 CYF -(Y = F, H, and PhSO 2 , respectively) in the gas phase and in Et 2 O solvent were studied theoretically. The nucleophilic fluoroalkylation of propylene oxide with fluorinated carbanions was probed by comparison of the reactivities (phenylsulfonyl)monofluoromethyl anion (PhSO 2 CHF -), the (phenylsulfonyl)difluoromethyl anion (PhSO 2 CF 2 -), and the bis(phenylsulfonyl)monofluoromethyl anion ((PhSO 2 ) 2 CFdoi:10.2298/jsc120831097h fatcat:yjpvxf3g3vaflpssjuqiyv6uwm