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Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell

Milivoj Lovrić
2019 Journal of Electrochemical Science and Engineering  
<p class="PaperAbstract">A model of reversible and quasi-reversible electrode reaction of dissolved redox couple is developed for the staircase voltammetry and the twin electrode thin layer cell. It is assumed that the neutral molecule is oxidized to a monovalent cation. The calculations were performed for the absence of supporting electrolyte and for its various concentrations. The influence of migration of cations and of IR<sub>Ω</sub> drop on the peak currents and peak potentials was
more » ... entials was investigated. Also, the kinetically controlled electrode reactions were simulated. These reactions can be distinguished from the reactions influenced by the resistance in the solution.</p>
doi:10.5599/jese.713 fatcat:oapmopktlnelrjv4iwpurtpzg4