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Termination Problems in Chemical Kinetics [chapter]

Gianluigi Zavattaro, Luca Cardelli
2008 Lecture Notes in Computer Science  
We consider nondeterministic and probabilistic termination problems in a process algebra that is equivalent to basic chemistry.  ...  Moreover, we show that the fairness intrinsic in stochastic computations implies that termination of all computation paths is undecidable, while it is decidable in a nondeterministic framework.  ...  This means that: (a) chemical kinetics is not Turing complete, (b) chemical kinetics is Turing complete up to any degree of precision, (c) existential termination is equally hard (decidable) in stochastic  ... 
doi:10.1007/978-3-540-85361-9_37 fatcat:babejy6x7zgojn2fiy6wtgj6wa

Page 60 of Journal of Engineering Mathematics Vol. 53, Issue 1 [page]

2005 Journal of Engineering Mathematics  
First, we discuss the chemical kinetics of the free-radical polymerization process, and formulate a mathematical model based on mass and heat balances in the system.  ...  The free- radical polymerization in question consists of a standard sequence of chemical reactions [7, Chapter 3].  ... 

Page 363 of The Journal of Chemical Physics Vol. 30, Issue 2 [page]

1959 The Journal of Chemical Physics  
THE JOURNAL OF CHEMICAL PHYSICS VOLUME 30, NUMBER 2 FEBRUARY, 1959 Kinetics and Molecular Weight Distributions for Unsteady-State Polymerizations Involving Termination by Chain Transfer with the Monomer  ...  problem.  ... 

Page 398 of International Chemical Engineering Vol. 13, Issue 3 [page]

1973 International Chemical Engineering  
We are concerned here with problems of chemical kinetics, in which the nature of the perturbations to the Maxwell-Boltzmann dis- tribution function is occasioned by chemical reactions; also included here  ...  kinetics problems.  ... 

Ab Initio Kinetic Modelling in Radical Polymerization: A Paradigm Shift in Reaction Kinetic Analysis

Michelle L. Coote, Christopher Barner-Kowollik
2006 Australian journal of chemistry (Print)  
We also discuss its advantages and possible problems, and highlight some of its potential applications in the radical polymer field.  ...  We describe a new rationale to kinetic modelling in which adjustable parameters are avoided through the use of quantum chemistry.  ...  -K. acknowledges funding from the ARC in the form of Discovery grants.  ... 
doi:10.1071/ch06194 fatcat:hyshteuu55h55o2lc4vwzue4ui

Some Problems in Chemical Kinetics and Reactivity

N. N. Semenov, Michel Boudart, Henry Wise
1959 Physics today  
INNECTICUT | Some Problems in Chemical Kinetics and Reac- tivity, Vol. 1 (2nd Revised Edition). By N. N. Seme- | nov. Translated from Russian by Michel Boudart. 239 pp. Princeton U.  ...  As pointed out in the introduction, this book is the outgrowth of a Symposium on Chemical Kinetics and Reactivity held in Moscow in 1955.  ... 
doi:10.1063/1.3060811 fatcat:hu25wyw6mze7tmjoplg46ohryu

Some problems of chemical kinetics and reactivity. Volume I. N. N. SEMENOV. Translated by J. E. S. BRADLEY, Pergamon Press, New York, London, Paris, 1958. x + 305 pp. $7.50

N. G. Gaylord, Frank R. Mayo
1959 Journal of Polymer Science  
XXXVIII, ISSUE 134 (1959) Some Problems of Chemical Kinetics and Reactivity. Volume I. N. N. Semenov. Translated by J. E. 8. Braptey, Pergamon Press, New York, London, Paris, 1958. x + 305 pp. $7.50.  ...  According to the Preface, this book was first published in 1954, to introduce an All- Union Conference on Chemical Kinetics and Reactivity, and to serve as a basis for discussion at that Conference.  ... 
doi:10.1002/pol.1959.1203813431 fatcat:buhn4ahdpnc7jeau6i6qrttcua

Influence of acoustic vibrations on the kinetics of liquid-phase chemical reactions involving associates

Kulagina TP, Smirnov LP, Andrianova ZS
2018 MOJ Bioorganic & Organic Chemistry  
Reaction product C is formed in the reaction B 2 + A 3 → C + B + 2A. 2 The system of kinetic equations for this reaction can be written in the form:  ...  The kinetics of bimolecular reactions is described by non-linear differential equations that admit the formation of dissipative structures of intermediate concentration. 3, 4 We assumed that in solution  ...  In our opinion, the influence of reagents association on the kinetics of chemical reactions deserves further basic and applied research.  ... 
doi:10.15406/mojboc.2018.02.0074 fatcat:agzslget6zbx5prejnnusefedm

Reactant subspaces and kinetics of chemical reaction networks

Carlene Perpetua P. Arceo, Editha C. Jose, Angelyn R. Lao, Eduardo R. Mendoza
2017 Journal of Mathematical Chemistry  
This paper studies a chemical reaction network's (CRN) reactant subspace, i.e. the linear subspace generated by its reactant complexes, to elucidate its role in the system's kinetic behaviour.  ...  We introduce concepts such as reactant rank and reactant deficiency and compare them with their analogues currently used in chemical reaction network theory.  ...  In Sect. 6, we discuss the problem of constructing a kinetic analogue of the stoichiometric subspace.  ... 
doi:10.1007/s10910-017-0809-x fatcat:73swieq7nfgfrjtgxxihe63q5e

Page 44 of Physics Today Vol. 12, Issue 5 [page]

1959 Physics Today  
INNECTICUT | Some Problems in Chemical Kinetics and Reac- tivity, Vol. 1 (2nd Revised Edition). By N. N. Seme- | nov. Translated from Russian by Michel Boudart. 239 pp. Princeton U.  ...  As pointed out in the introduction, this book is the outgrowth of a Symposium on Chemical Kinetics and Reactivity held in Moscow in 1955.  ... 

Some problems of chemical kinetics and reactivity. Volume 1. ; Some Problems in chemical kinetics and reactivity. Volume 1

E. W. R. Steacie
1959 Journal of Chemical Education  
In recent years there has been rather a split in outlook between Western work and that in Seme- ‘1omogeneous Solution Volume 5 N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity.  ...  Some Problems in Chemical Kinetics and Reactivity. Volume I N. NV. Semenov. Translated by Michel Boudart. Princeton University Press, Princeton, N. J., 1958. xii + 239 pp.  ... 
doi:10.1021/ed036p475.1 fatcat:gon3f4iyx5dbpnmx4y7w5hy6eq

Page 152 of Chemical Engineering Vol. 66, Issue 2 [page]

1959 Chemical Engineering  
METAL TEXTILE CORPORATION .. world’s largest and oldest producer of knitted wire products A DIVISION OF GENERAL CABLE CORPORATION Provocative and Stimulating SOME PROBLEMS IN CHEMICAL KINETICS AND REACTIVITY  ...  A first edition of the book was originally written by Seme- nov as a survey of the litera- ture and personal critique for a Russian Symposium on Chemical Kinetics and Reactivity in 1955.  ... 

Conference Report: Chemical kinetics - theory and experiment

J.T. Herron, W. Tsang
1985 Journal of Research of the National Bureau of Standards  
This is indicative of the exciting developments in chemical kinetics in recent years.  ...  The purpose of the conference was to bring together investigators from a broad range of institutions and backgrounds to review progress and problems in theoretical and experimental chemical kinetics.  ... 
doi:10.6028/jres.090.027 pmid:34566166 pmcid:PMC6692289 fatcat:4pfeizeakrdutnyi7tkqelnisi

Positive equilibria of power law kinetics on networks with independent linkage classes [article]

Bryan S. Hernandez, Eduardo R. Mendoza
2022 arXiv   pre-print
In this work, we show that a cycle terminal PL-FSK system with E_+∅ and has independent linkage classes (ILC) is a poly-PLP system, i.e., E_+ is the disjoint union of log-parametrized sets.  ...  In particular, we obtain a species hyperplane containment criterion to determine ACR in the system species.  ...  One can deal with extensions of results for poly-PL kinetics (non-negative linear combination of power law kinetics) and Hill-type.  ... 
arXiv:2111.07122v2 fatcat:53uvzaembzbtfpjvrivklaathq

Existence of Positive Steady States for Mass Conserving and Mass-Action Chemical Reaction Networks with a Single Terminal-Linkage Class [article]

Santiago Akle, Onkar Dalal, Ronan M. T. Fleming, Michael Saunders, Nicole Taheri, Yinyu Ye
2011 arXiv   pre-print
We establish that mass conserving single terminal-linkage networks of chemical reactions admit positive steady states regardless of network deficiency and the choice of reaction rate constants.  ...  Our proof uses a fixed point of a novel convex optimization formulation to find the steady state behavior of chemical reaction networks that satisfy the law of mass-action kinetics.  ...  Thus, we seek properties of chemical reaction networks that are independent of kinetic parameters.  ... 
arXiv:1105.2359v3 fatcat:7baejgazf5gf7dfqkqxjsrcvii
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