[Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0)
release_rev_a6db4e51-8167-45cb-9995-373200953755
by
N. Peulecke,
S. Peitz,
B.H. Müller,
A. Spannenberg,
U. Rosenthal,
University, My
2020
Abstract
The title compound, [Cr(C26H26P2Si)(CO) 4], was obtained by the reaction of Ph2PSiMe 2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 80.27 (1)°.
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10.34657/4048
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