BibTeX
CSL-JSON
MLA
Harvard
QSAR of Reaction Between Hydrazine and Its Derivatives With Nitrous Acid
release_cdbzwpv67ndefn5gz366abmpdu
by
NIE Jiang,
YANG Shu-ming,
LI Ming-ming,
YANG Ya-ya,
LIU Xiao-juan,
OUYANG Ying-gen,
XIAO Song-tao
Published
in Journal of Nuclear and Radiochemistry
by Editorial Office of Journal of Nuclear and Radiochemistry.
2022 Volume 44, p207-213
Abstract
In this paper, the half-reaction time of the reaction between hydrazine and its derivatives with nitrous acid is measured using spectrophotometry and stopped-flow injection device. Using Gaussian09 and HyperChem, hydrazine and its derivatives have been structurally optimized and some quantization parameters are calculated. Combining the half-reaction time and the quantization parameters, and using statistical regression analysis, QSAR model of the reaction between hydrazine and its derivatives with nitrous acid is established. The results show that total energy of molecules is the most important influencing factor in the reaction, and the half-reaction time increases with total energy of the molecule except for allyl hydrazine, the reaction rate decreases with the increase of total energy of the molecule.
In text/plain format
Archived Files and Locations
application/pdf
758.7 kB
file_r46orghsxraefa2x7vw5enlxr4
|
www.jnrc.org.cn (web) web.archive.org (webarchive) |
Read Archived PDF
Preserved and Accessible
Work Entity
access all versions, variants, and formats of this works (eg, pre-prints)
access all versions, variants, and formats of this works (eg, pre-prints)
Cite This
Lookup Links
oaDOI/unpaywall (OA fulltext)
Crossref Metadata (via API)
Worldcat
SHERPA/RoMEO (journal policies)
wikidata.org
CORE.ac.uk
Semantic Scholar
Google Scholar
Crossref Metadata (via API)
Worldcat
SHERPA/RoMEO (journal policies)
wikidata.org
CORE.ac.uk
Semantic Scholar
Google Scholar