Elegant synthesis of novel pyrroles and dipyrrylmethane of biosynthetic importance
release_3sqgs6iubrfxxflbck53yuygpm
by
Vandana Singh,
Abdul Baqi
2002
Abstract
Department of Chemistry, University of Allahabad, Allahabad-21 1 002, India <em>E-mail : </em>singhvandanasingh@rediffmail.com <em>Manuscript received 30 </em><em>May </em><em>2001. revised 12 November 2001, accepted 21 March 2002</em> Ethyl 4-ethoxycarbonylinethyl-3,5-dimethylpyrrole-2-carboxylate (1) has been synthesized by extension and modification of Knorr pyrrole synthesis. Its acetoxymethyl derivative (2) has also been synthesized. Diethyl 3,3'-bis(ethoxycarbonylmethyl)-4,4<sup>'</sup>-dimethyl2,2'-dipyrrylmethane-5,5<sup>1</sup>-dicarboxylate has been synthesized by self-condensation of 2<strong>.</strong>
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